Abstract. Mineral hydration is an important geological process that
influences the rheology and geochemistry of rocks and the fluid budget of
the Earth's crust and mantle. Constant-stress differential compaction
(CSDC) tests, dry and “wet” tests under confining pressure, and axial-stress tests were
conducted for the first time to investigate the influence of triaxial
stress on hydration in anhydrite–gypsum aggregates. Characterization of the
samples before and after triaxial experiments was performed with optical
and scanning electron microscopy, including energy-dispersive spectroscopy
and electron backscatter diffraction mapping. Stress–strain data reveal that
samples that underwent constant-stress differential compaction in the
presence of fluids are ∼ 14 % to ∼ 41 % weaker
than samples deformed under wet conditions. The microstructural analysis
shows that there is a strong temporal and spatial connection between the
geometry, distribution, and evolution of fractures and hydration products.
The increasing reaction surface area in combination with pre-existing gypsum
in a gypsum-bearing anhydrite rock led to rapid gypsification. The
crystallographic orientations of newly formed vein gypsum have a systematic
preferred orientation for long distances along veins, beyond the grain
boundaries of wall-rock anhydrite. Gypsum crystallographic orientations in
{100} and {010} are
systematically and preferentially aligned parallel to the direction of
maximum shear stress (45∘ to σ1). Gypsum is also not
always topotactically linked to the wall-rock anhydrite in the immediate
vicinity. This study proposes that the selective inheritance of crystal
orientations from favourably oriented wall-rock anhydrite grains for the
minimization of free energy for nucleation under stress leads to the
systematic preferred orientation of large, new gypsum grains. A sequence is
suggested for hydration under stress that requires the development of
fractures accompanied by localized hydration. Hydration along fractures with
a range of apertures up to 120 µm occurred in under 6 h. Once
formed, gypsum-filled veins represent weak surfaces and are the locations of
further shear fracturing, brecciation, and eventual brittle failure. These
findings imply that non-hydrostatic stress has a significant influence on
hydration rates and subsequent mechanical strength of rocks. This phenomenon
is applicable across a wide range of geological environments in the Earth's
crust and upper mantle.