“…1 H NMR (400 MHz, CDCl 3 ): δ 8.06−8.01 (m, 2H), 7.46 (d, J = 8.8 Hz, 2H), 6.73 (br, 1H), 1.54 (s, 9H); spectroscopic data consistent with the literature. 44 4-((tert-Butoxycarbonyl)(methyl)amino)benzoic Acid (17b). 4-(Methylamino)benzoic acid 16b (1 equiv, 13.2 mmol, 2.0 g) was solubilized in MeOH (16 mL) and water (16 mL) and NaHCO 3 (2 equiv, 26.5 mmol, 2.25 g) was added.…”