The phenomenon of spontaneous imbibition is widely present in the development process of tight oil/gas reservoirs. To further explore the spontaneous imbibition behavior of capillary tubes to provide theoretical and methodological references for the study of microscopic porous media imbibition phenomena, the capillaries that can be observed with the naked eye on the order of 10–100 μm were selected as research objects. Based on the theory of interface chemistry, the capillary end effect, and wetting hysteresis, the influence of the additional pressures generated by the two-phase interface on the spontaneous absorption of the horizontal capillary was studied. Some of the capillaries were processed for wettability, and then the water wettability of different capillaries was measured by the introduced concept, which is the conversion height of the self-absorption phase in the capillary. The capillaries were horizontally placed in the liquid for a spontaneous imbibition experiment, and the air–liquid two-phase menisci behavior was observed at the same time, and then the influence of water wettability, surfactant, and capillary diameter on spontaneous imbibition was discussed. It was found that in the equal diameter capillaries, the spontaneous air–liquid imbibition behavior of capillary tubes with different water wetting properties is different in sensitivity to surfactants and tube diameters; when surfactants are used to improve capillary water wettability to increase spontaneous imbibition efficiency, the initial water wettability of the capillary and the comprehensive changes in the capillary pressure caused by interfacial tension should be considered.

Aiming at the phenomenon that the emulsification degree of the composite oil displacement agents affects the recovery factor, composite oil displacement agents of the P/S binary system and the A/S/P ternary system were taken as research objects. Emulsion particle size and stability were tested and evaluated, and the effects of the surfactant and alkali content on the emulsification degree of emulsion were investigated. The concept of the emulsification stability index and its measuring method were put forward, and a method was used to test and evaluate the emulsification stability of the emulsion. The results showed that the emulsion formed by the ternary system had the smallest average particle size, the best stability, and the best emulsification stability. The binary composite system was second, and the polymer solution did not form an emulsion. The emulsification stability index method could effectively quantify the emulsification degree of the emulsion. Within a certain range, the increase of the surfactant and alkali content in the composite oil displacement agent was beneficial to the improvement of the emulsification degree of the emulsion.