Bauxites and Fe laterites were formed on Neogene volcanics from Fongo-Tongo region in the highlands of western Cameroon, and are distributed on plateaus, slopes and downslope surfaces. Bauxitic profiles result from intense in-situ weathering of trachytes that implied depletion of silica and labile elements from the saprolite, while alumina relatively accumulated from parent minerals pseudomorphosis by primary gibbsite formation. During ongoing lateritization and bauxite maturation, important leaching and illuviation processes resulted in secondary gibbsite crystallizations. Late incision and dissection of upper bauxitic plateau resulted in degradation and dismantling of bauxitic duricrusts with Fe-depletion and increasing silica. Compared to trachyte, bauxitic duricrusts are relatively enriched in Nb, Zr,