Ground
subsidence caused by permafrost thawing causes
the formation
of thermokarst ponds, where organic compounds from eroding permafrost
accumulate. We photolyzed water samples from two such ponds in Northern
Quebec and discovered the emission of volatile organic compounds (VOCs)
using mass spectrometry. One pond near peat-covered permafrost mounds
was organic-rich, while the other near sandy mounds was organic-poor.
Compounds up to C10 were detected, comprising the atoms of O, N, and
S. The main compounds were methanol, acetaldehyde, and acetone. Hourly
VOC fluxes under actinic fluxes similar to local solar fluxes might
reach up to 1.7 nmol C m–2 s–1. Unexpectedly, the fluxes of VOCs from the organic-poor pond were
greater than those from the organic-rich pond. We suggest that different
segregations of organics at the air/water interface may partly explain
this observation. This study indicates that sunlit thermokarst ponds
are a significant source of atmospheric VOCs, which may affect the
environment and climate via ozone and aerosol formation. Further work
is required for understanding the relationship between the pond’s
organic composition and VOC emission fluxes.