THE ACTIVITIES OF ZINC, CADMIUM, TIN, LEAD AND BISMUTH IN THEIR BINARY LIQUID MIXTURES¹

Influence of Ag on the activity of Zn in {(1−x1−x2)Sn+x1Zn+x2Ag}(l) atT=903 K

“…This alloy was examined many times by different authors, who used different experimental methods, (6) like the SEM method, (7)(8)(9)(10)(11)(12)(13)(14)(15)(16) the calorimetric method, (12,(17)(18)(19) vapour pressure measurements, (20)(21)(22)(23)(24)(25)(26) and the torsion method. (27,29) There are many experimental results, either for a very limited range of zinc concentration or for temperatures higher or lower than the temperature of the experiments carried out, i.e.…”

“…(27,29) There are many experimental results, either for a very limited range of zinc concentration or for temperatures higher or lower than the temperature of the experiments carried out, i.e. T = 903 K. (7,10,11,15,16,24,27,35) The experiments for the widest range of concentration of Zn and for temperatures near T = 903 K were carried out by Ptak (11) (for T = 950 K) and Mu¨ller (26) T = (723 to 973) K. The equation proposed by Ptak (11) is as follows:…”

Electromotive Force Measurements in High-Temperature Systems

“…Concentration cells without transference appeared to be more convenient to study metallic systems. Consequently, this kind of research was initiated by Taylor (1923) and Seltz (1935). Working with cells with transference the main problem connected with this construction was a junction between half-cells and generated junction potential.…”

Thermodynamic reassessment of the Cd−Zn system

“…The enthalpy of mixing of the liquid alloys from emf measurements was determined by Sano et al [22], Wynnemer and Preckshot [23] and Bohl and Hilderbrandt [24], or by calorimetry measurements from Oelson et al [13], Kleppa [25] and Wittig et al [26]. The activity of zinc in the liquid was determined using the fused salt emf method by Sano et al [22], Bohl and Hilderbrandt [24], Taylor [27], Moser [28] and Chung et al [29], using the solid electrode emf method by Katayama et al [30], using the vapor pressure measurements by Kozuka et al [31], using the transport method by Ban-ya and Maruyama [32], and using the Kunudsen cell-quadrupole mass filter method by Nakazawa et al [33].…”