Arsenic ions of 100 keV are implanted into misaligned (111) ‐silicon crystals with doses of 1 × × 1014, 5 × 1014, 1 × 1015, 5 × 1015, and 1 × 1016 ions/cm2. After 30 min annealing at 600 and 800 °C the carrier density distributions are derived from measurements of Hall effect and sheet conductivity in combination with successive layer stripping. Moreover, proton backscattering spectra for as‐implanted silicon and arsenic range distributions obtained by SIMS analysis are used for comparison. The reverse annealing behaviour observed for ion doses equal or greater than 5 × 1014 As+/cm2 is explained as a relaxation to the equilibrium.