The antisymbiotic effect in some iridium(III) hydrides with N-, O-, and S-donor ligands

Crabtree, Robert H.; Davis, Mark W.; Mellea, Michelle F.; Mihelcic, Jean M.

doi:10.1016/s0020-1693(00)81723-5

Cited by 21 publications

(2 citation statements)

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“…Crabtree and co-workers reported that the electrophilic iridium complex, Ir3+, could be stabilized by nitrobenzene. 58 Once again a parallel between haloalkane complexes and nitroarene complexes could be drawn. These studies clearly demonstrate the very weak nucleophilic behavior of nitroaromatics.…”

Section: Discussionmentioning

confidence: 94%

Homogeneous catalytic carbonylation of nitroaromatics. 5. Kinetics and mechanism of aniline and carbamate formation using ruthenium complex Ru(Ph2PCH2CH2PPh2)(CO)3

et al. 1992

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Section: Discussionmentioning

confidence: 94%

Homogeneous catalytic carbonylation of nitroaromatics. 5. Kinetics and mechanism of aniline and carbamate formation using ruthenium complex Ru(Ph2PCH2CH2PPh2)(CO)3

et al. 1992

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“…The carbonylation reaction of nitro-aromatics is an exothermic reaction and is catalyzed by palladium, ruthenium, and to a lesser extent rhodium. Furthermore, platinum [44], iridium [45], and iron [46] have also been reported to be active in this reaction. For a reductive carbonylation of aromatic nitro-compounds carried out in alcohol, it might generally be considered that the carbamate 15 is formed by reaction of aromatic isocyanates ArNCO, with an alcohol R-OH, outside the coordination sphere of the metal [47].…”

Section: Reductive Carbonylation Of Nitro-aromaticsmentioning

confidence: 99%

Recent Developments on the Carbamation of Amines

Chaturvedi

2011

COC

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Organic carbamates represent an important class of compounds showing various interesting properties. They find wide utility in various areas as pharmaceuticals, agrochemicals (pesticides, herbicides, insecticides, fungicides etc.), intermediates in organic synthesis, protection of amino group in peptide chemistry, and as linker in combinatorial chemistry etc. Classical synthesis of carbamates involves use of harmful reagents such as phosgene, its derivatives and carbon monoxide. Recently, various kinds of synthetic methods have been developed for the synthesis of organic carbamates. In the present review, I would like to highlight the recent developments on the synthesis of organic carbamates using variety of reagents.

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Coordination Chemistry of Transition Metals with Hydrogen Chalcogenide and Hydrochalcogenido Ligands

Peruzzini

Ríos

Romerosa

2001

Progress in Inorganic Chemistry

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The antisymbiotic effect in some iridium(III) hydrides with N-, O-, and S-donor ligands

Cited by 21 publications

References 20 publications

Homogeneous catalytic carbonylation of nitroaromatics. 5. Kinetics and mechanism of aniline and carbamate formation using ruthenium complex Ru(Ph2PCH2CH2PPh2)(CO)3

Homogeneous catalytic carbonylation of nitroaromatics. 5. Kinetics and mechanism of aniline and carbamate formation using ruthenium complex Ru(Ph2PCH2CH2PPh2)(CO)3

Recent Developments on the Carbamation of Amines

Coordination Chemistry of Transition Metals with Hydrogen Chalcogenide and Hydrochalcogenido Ligands

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