Artificial intelligence is an innovative enterprise theme that combines computer science, physiology, science, and other disciplines, including expert programs, technical experiments, games, native language understanding, cognitive rehabilitation, robotics, engineering, recognition, and other fields. The breakthrough growth made the arrival of the era of big data have a fundamental impact on many traditional industries and has also promoted the transformation of teaching methods and methods in the field of education. In the traditional classroom, due to the limitations of teaching resources, teaching time, and location, students are basically passively accepted by the teacher, and the teaching form is single. This will improve in the age of big data with well-developed network message. Modern distance education uses advanced technology such as computer networks, multimedia, and artificial intelligence to build a virtual teaching environment based on the network. It breaks through the limitations of teachers, teaching materials, experimental equipment, and other resources that exist under the traditional teaching model. Using educational resources of the same scale can expand educational capabilities exponentially and at the same time overcomes the unified progress of traditional teaching methods, single teaching methods, and students’ dissatisfaction. The shortcomings of differences and personalities that are not reflected are conducive to the improvement of the quality of education. It is the original intention of education to offer students special study resources and to stimulate students’ enthusiasm for learning. To enhance the current learning environment, the article builds a personalized multimedia network teaching system based on big data and streaming media technology. By recording the teacher’s class process as a video and uploading it to the multimedia network teaching system, students can watch and download related videos online for learning and also communicate online. The system can also provide personalized and intelligent recommendations for students based on student learning habits. The system is developed based on intelligent multimedia method and has the characteristics of security and stability and has done some help for network teaching of educational institutions.