The application of the polarographic method to the study of the kinetics of polymerization and copolymerization with styrene of 4-vinyldiphenyl and its derivatives

Bezuglyi, V. D.; Alekseyeva, T.A.; Dmitriyevskaya, L.I.; Chernobai, A.V.; Kruglyak, L.P.

doi:10.1016/0032-3950(64)90355-7

Cited by 5 publications

(4 citation statements)

References 4 publications

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“…Methyl methacrylate, for example, is readily reduced at the electrode to methyl isobutyrate (172). Since different monomers show different activities (different reactions at different applied voltages), the polarographic method has the useful feature of being able to allow the simultaneous determination of the concentrations of more than one monomer in a copolymerizing system (54,55). In this method the usual procedure is to separate the polymer from the reaction system prior to the polarographic analysis.…”

Section: Survey Of Experimental Methodsmentioning

confidence: 99%

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Photopolymerization of vinyl monomers

Oster¹,

Yang²

1968

Chem. Rev.

247

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Section: Survey Of Experimental Methodsmentioning

confidence: 99%

“…In such cases the monomer can be chemically converted into a derivative of manageable polarographic characteristics (55). Since the diffusion rates of polymer and of monomer differ so widely, it might be possible to carry out the polarographic analysis in situ.…”

Section: Survey Of Experimental Methodsmentioning

confidence: 99%

Photopolymerization of vinyl monomers

Oster¹,

Yang²

1968

Chem. Rev.

247

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“…469 " 476 Betso and McLean 468 applied d.p.p. to the determination of the acrylamide monomer in polyacrylamide; possible and actual interfering compounds and their removal were studied.…”

Section: Acrylamide In Polyacrylamidementioning

confidence: 99%

Applied Polarography and Voltammetry of Organic Compounds in Pratical Day-To-Day Analysis Part II

Bersier¹,

Bersier²,

Zuman³

1985

C R C Critical Reviews in Analytical Chemistry

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“…Polymerization of derivatives of 4vinylbenzene and styrene (66), change in structure of stilbene and naphthalene upon exposure to ultraviolet radiation {431), and addition reactions with unsaturated systems {243) were followed polarographically. Reduction kinetics for several aromatic hydrocarbons were reported {110).…”

Section: Irreversible Systemsmentioning

confidence: 99%

Organic Polarography

Pietrzyk¹

1966

Anal. Chem.

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HIS REVIEW covers articles which T have appeared in Chemical Abstracts and readily available journals during the two-year period ending November 1, 1965. As in the past, duplications and reinvestigations of previous work appear widely, and the tendency for authors to publish the same work in more than one journal has continued.This period has seen the publication of a special issue of Talanta honoring the 70th year for Professor Izaak If. Kolthoff (411). This issue is comprised entirely of invited contributions of his former students and associates and a list of Professor Kolthoff's past publications. Best wishes go to Professor Kolthoff for many more years of fruitful labor.Polarographic advances in Japan ( m 4 , 800, 801) and in Prague (429) were reviewed. The use of electron spin resonance spectrometry in evaluating electrode reactions in which free radicals are formed has continued t o grow (3, 25). Books dealing with "Polarography of Polymers'' (64) and "Organic Polarographic Analysis" (947) hare been published. Two books containing a listing of literature covering polarography through 1964 also became available (340,341 ) Yunierous reviews have appeared on the applications of polarography to pesticide analysis (98,224,226,524), lignin chemistry (627), cytostatically active compounds ($239, smoke analysis (700), proteins (114, 567,893), pharmaceuticals and drugs (1 74, 242, 249,329, 659,917), petroleum analysis (171 , 318,942), polymers (63), biocheniical analysis (661)) feed medicament analysis (9), clinical chemistry (104) , and enzyme activity (435). Other reviews have covered organic analysis (119,169,830,331) , organic polarography (496, 543, 583,773,805,897,914,946) and application to electrochemical synthesis (28.5) * Specialized polarographic reviews were concerned with alkaloids and their analysis (706), the effect of pH on halfwave potentials (176), utilization in assigning ring and chain structures and following the rate of tautomerism (344), polarography of enediols (log), substituted 3-phenyl-sydnones (767) , carbon disulfide and derivatives (639) and organic peroxides (269), the study of electron and proton transfer (6), the progress and problems in electrode kinetics (84) and the techniques for studying kinetics of oxidation (210).Reviews on adsorption of organic compounds at electrode surfaces (13, 218,443) and effect on reduction (493), a theoretical treatment of adsorption (136), and studies in adsorption isotherms (148) have appeared. Oscillographic and alternating current polarography were used to study the effects of anionic, cationic, and neutral surface active agents on polarographic analysis (337). Additional studies on adsorption are included under specific compounds.Studies in nonaqueous media have been reviewed (199,253,412). Other studies, however, mere concerned with the effects of different solvents on polarographic active compounds ($11, 71 9 ) .Work on the correlation of half-wave potentials with various constants continues. The relationship between halfwave potential...

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The application of the polarographic method to the study of the kinetics of polymerization and copolymerization with styrene of 4-vinyldiphenyl and its derivatives

Cited by 5 publications

References 4 publications

Photopolymerization of vinyl monomers

Photopolymerization of vinyl monomers

Applied Polarography and Voltammetry of Organic Compounds in Pratical Day-To-Day Analysis Part II

Organic Polarography

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