The Auger parameter and the study of chemical and electronic interactions at the Sb2Ox/SnO2 and Sb2Ox/Al2O3 interfaces

Reiche, R.; Dobler, Dorota; Holgado, Juan P.; Barranco, Ángel; Martín-Concepción, A. I.; Yubero, F.; Espinós, J. P.; González‐Elipe, Agustín R.

doi:10.1016/s0039-6028(03)00606-x

“…It was observed that the valance band spectra of Sb(V) and Sb(III) are different. 11,12) The valence band photoelectron spectrum of Sb 2 O 3 (Fig. 4(b)) showed peaks at around 4.0, 8.0, and 12.0 eV, which matched the literature value.…”

Section: Xps Analysis Of Sb-deposited Samplessupporting

confidence: 86%

Studies on Sorption of Antimony on Carbon Steel Surface in Chemical Decontamination Medium

Mittal¹,

Bera²,

Velmurugan³

et al. 2011

J. Nucl. Sci. Technol.

0

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Antimony(III) in a mixed solution of nitrilo tri acetic acid, ascorbic acid, and citric acid, known as a chemical decontamination solution, was found to be deposited on a carbon steel (CS) surface under deaerated condition. The deposited antimony on the CS surface was characterized by X-ray photoelectron spectroscopy and X-ray diffraction technique. The deposited material was found to contain elemental Sb and the Fe-Sb-O compound. The characterization results showed the initial adsorption of Sb on CS and the subsequent surface precipitation of the Fe-Sb-O compound. A commercial organic inhibitor Rodine 92B was used to stop the initial adsorption of Sb(III) and further growth of the Fe-Sb-O compound on the CS surface. Nitrogen in the inhibitor was observed to act as the bridging agent between Fe and the inhibitor for growing a layer of the inhibitor that stopped the adsorption of Sb. The work has direct relevance to nuclear reactors in terms of prevention of deposition of radioactive antimony on CS surfaces during chemical decontamination.

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“…This implies that Sb 3+ and Sb 5+ replace Sn 4+ in the rutile lattice. The two kinds of dopants can act as acceptor and donor, respectively [16][17][18][19]. When the samples were prepared, the process of substitution of Sb ions can be depicted by Seto [20] as…”

Section: Resultsmentioning

confidence: 99%

Structural and photoluminescence characters of SnO2:Sb films deposited by RF magnetron sputtering

Wang

¹

,

Ma

²

,

Jin

³

et al. 2005

Journal of Luminescence

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“…4(b)) showed peaks at around 4.0, 8.0, and 12.0 eV, which matched the literature value. 10,11) The peaks at 4.0 and 12.0 eV had contribution from the lone pair electrons (5s) in Sb 2 O 3 and, hence, were characteristic of the Sb(III) chemical state. Another peak of the Sb(III) compound at around 8.0 eV was a result of hybridization of O-2p with 5p/5s electrons of Sb.…”

Section: Xps Analysis Of Sb-deposited Samplesmentioning

confidence: 99%

Studies on Sorption of Antimony on Carbon Steel Surface in Chemical Decontamination Medium

Mittal¹,

Bera²,

Velmurugan³

et al. 2011

Journal of Nuclear Science and Technology

View full text Add to dashboard Cite

Antimony(III) in a mixed solution of nitrilo tri acetic acid, ascorbic acid, and citric acid, known as a chemical decontamination solution, was found to be deposited on a carbon steel (CS) surface under deaerated condition. The deposited antimony on the CS surface was characterized by X-ray photoelectron spectroscopy and X-ray diffraction technique. The deposited material was found to contain elemental Sb and the Fe-Sb-O compound. The characterization results showed the initial adsorption of Sb on CS and the subsequent surface precipitation of the Fe-Sb-O compound. A commercial organic inhibitor Rodine 92B was used to stop the initial adsorption of Sb(III) and further growth of the Fe-Sb-O compound on the CS surface. Nitrogen in the inhibitor was observed to act as the bridging agent between Fe and the inhibitor for growing a layer of the inhibitor that stopped the adsorption of Sb. The work has direct relevance to nuclear reactors in terms of prevention of deposition of radioactive antimony on CS surfaces during chemical decontamination.

show abstract

The Auger parameter and the study of chemical and electronic interactions at the Sb2Ox/SnO2 and Sb2Ox/Al2O3 interfaces

Cited by 21 publications

References 35 publications

Studies on Sorption of Antimony on Carbon Steel Surface in Chemical Decontamination Medium

Studies on Sorption of Antimony on Carbon Steel Surface in Chemical Decontamination Medium

Structural and photoluminescence characters of SnO2:Sb films deposited by RF magnetron sputtering

Studies on Sorption of Antimony on Carbon Steel Surface in Chemical Decontamination Medium

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