This study examines the role of Education in women empowerment for effective participation in National Development. Education is a very important tool in improving the status of women in any society. It is indispensable as it enables women to gain Knowledge about the world which helps women upgrade their status, gain positive self-esteem, self-confidence, and necessary strength needed to face challenges in life. Therefore, educated women have a vital role to play in governance, agricultural sector, industrial sector, and the commerce sector for the nations building. Although Nigeria women are faced daily with some grassroots challenges that have hindered their participation in the nations building. The challenges faced by women daily which have limited their contributions to the development of Nigerian economy includes; cultural and traditional belief system, religion, illiteracy and low standard of living. The study concluded that, across the country women access to education is still low as the gender disparity in the enrolment of women into all level of educational institutions has widened over the years. To bridge this gap, the government should as a matter of urgency create and implement policies capable of promoting gender balance in access to education across the country, by insisting on the enrolment of a higher percentage of girl child in schools from primary schools. The government should also create policies that can remove institutional and artificial barriers based on culture, religion and traditional considerations impeding women from contributing to economic development.