1981
DOI: 10.1021/j150617a005
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The chemiluminescent reaction of ozone with methyl mercaptan

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Cited by 22 publications
(13 citation statements)
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“…S-H bonds, which have a lower bond energy (bonding energy, 347.3 kJ mol À1 ), were most easily dissociated from the CH 3 SH molecular structure, and some S-C bonds were disjointed [31]. We confirmed the mechanism of by-products formed by EB and plasma in previous studies, which is divided into three steps [31,[44][45][46][47]. The first step is CH 3 SH, which is converted into CH 3 S, CH 3 …”
Section: Ch 3 Shsupporting
confidence: 83%
See 1 more Smart Citation
“…S-H bonds, which have a lower bond energy (bonding energy, 347.3 kJ mol À1 ), were most easily dissociated from the CH 3 SH molecular structure, and some S-C bonds were disjointed [31]. We confirmed the mechanism of by-products formed by EB and plasma in previous studies, which is divided into three steps [31,[44][45][46][47]. The first step is CH 3 SH, which is converted into CH 3 S, CH 3 …”
Section: Ch 3 Shsupporting
confidence: 83%
“…The mechanism of the formation can be distinguished into three steps based on our results, and those of previous studies using plasma and UV [14,[16][17][30][31][43][44][45] …”
Section: H 2 Ssupporting
confidence: 59%
“…However, no bands due to triplet S02(3B,) were observed in these reactions as reported by Halstead and Thrush (3) in the chemiluminescent emission from reaction [I]. Recently, Glinski et al (4,5 ) have reexamined the reactions of O, with CH3SH and H2S under beam-gas conditions and shown that the vibrationally resolved phosphorescent spectra are due to first triplet excited state of SO2.…”
Section: Imentioning
confidence: 77%
“…•V'-'iTrd h + h (23) at pressures near 20 mTorr, when k7 < {h + &6)[M], predicting a zero-order dependence. But above 4 mTorr, the quenching frequency of the triplet, fc8[M], becomes greater than the reciprocal lifetime, k9, and a 1/[M] dependence is predicted.…”
Section: Modeling Results and Discussionmentioning
confidence: 99%