1970
DOI: 10.1039/j19700000238
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The chemistry of copper(I) complexes. Part I. Halogeno-complexes

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Cited by 126 publications
(57 citation statements)
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“…The solutions of copper(1) complex from phen, bpy, and DTH were stable under nitrogen and also were hardly photolabile. The phosphine complexes, Cu(acac) (PPh,)?, and probably other analogues (16)(17)(18)(19), were most stable presumably due to extensive back bonding and could be handled under ambient conditions indefinitely. At the other extreme were the cases of the sensitized photoreduction in the presence of diglyme and norbornene in which copper metal was almost immediately formed as the blue solution started to bleach.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The solutions of copper(1) complex from phen, bpy, and DTH were stable under nitrogen and also were hardly photolabile. The phosphine complexes, Cu(acac) (PPh,)?, and probably other analogues (16)(17)(18)(19), were most stable presumably due to extensive back bonding and could be handled under ambient conditions indefinitely. At the other extreme were the cases of the sensitized photoreduction in the presence of diglyme and norbornene in which copper metal was almost immediately formed as the blue solution started to bleach.…”
Section: Resultsmentioning
confidence: 99%
“…It is well known that certain copper(l1) complexes are readily reduced by phosphines (16)(17)(18)(19) and electrolysis (43). In spite of the difficulty encountered in the isolation of the copper(1) complexes, the present sensitized photoreduction demonstrates an advantageous route to prepare certain copper(1) complexes that are difficult to prepare by conventional reduction methods.…”
Section: Resultsmentioning
confidence: 99%
“…The compound was synthesized by the method of Jardine, Rule & Vohra (1970) and was recrystallized from THF/pentane. A small crystal (0.40 x 0.40 × 0.40 mm) was selected and transferred to the goniostat where it was cooled to 115 K for characterization and data collection.…”
Section: Introductionmentioning
confidence: 99%
“…After cooling to room temperature, the resulting white solids were collected by filtration to afford 1.06 g (87.2% yield) of the desired product, mp 240 o C (lit. 20 248 o C).…”
Section: Methodsmentioning
confidence: 99%
“…20 In a 100 mL round-bottomed flask were placed 1.71 g (10 mmol) of copper (II) chloride dihydrate and 90 mL of ethanol. The resulting mixture was heated to reflux and 3.93 g (15 mmol) of triphenyl phosphine was added in small portions.…”
Section: Tetrakis-[chlorotriphenylphosphinecopper(i)] [Cuclpph 3 ]mentioning
confidence: 99%