The chemistry of furfuryl alcohol resins

Barr, J.B.; Wallon, S. B.

doi:10.1002/app.1971.070150504

Cited by 95 publications

(70 citation statements)

References 10 publications

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“…[34] Scheme 1 shows the reaction pathways of furfural hydrogenation with furfuryl alcohol as one of the most common products, which is used in the production of thermostatic resins and fiber-reinforced plastics. [29,36] Cu, [37] Ni [38] or Ru [39] based catalysts have been investigated for furfural hydrogenation and have shown good catalytic properties but under harsh reaction conditions, either at high temperature or with high hydrogen pressure. Pd is an ideal catalyst for hydrogenation of furfural because of the capability to dissociate hydrogen under ambient conditions.…”

Section: Introductionmentioning

confidence: 99%

Tailoring the 3D Structure of Pd Nanocatalysts Supported on Mesoporous Carbon for Furfural Hydrogenation

Villa

Kübel

et al. 2018

ChemNanoMat

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By quantitative 3D structural characterization of Pd nanoparticles supported on mesoporous carbon, we identify the most important structural aspects of the catalysts, which are responsible for the activity, selectivity and stability in liquid phase furfural hydrogenation. A systematic series of catalysts were prepared by three synthetic methods: incipient wetness impregnation, wet impregnation and immobilization of preformed PVA stabilized nanoparticles in order to control the Pd nanoparticle distribution on the external and internal surfaces of the mesoporous carbon. The activity and selectivity of these catalysts are highly affected by the particle locations. More Pd nanoparticles located inside pores promote the formation of 2‐methyl furan, while selectivity to furfuryl alcohol and tetrahydrofurfuryl alcohol is suppressed correspondingly. Through recycling tests we find that leaching depends on the synthesis process and plays an important role with respect to catalytic stability.

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Section: Introductionmentioning

confidence: 99%

Tailoring the 3D Structure of Pd Nanocatalysts Supported on Mesoporous Carbon for Furfural Hydrogenation

Villa

Kübel

et al. 2018

ChemNanoMat

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“…This means that F‐alginate has a specific group that is analogous with furfurylamine. The reason for the absorption wavelength shift of F‐alginate is based on electron delocalization from the amide bond of modified alginate . These results indicate that a furfuryl group was successfully introduced in alginate.…”

Section: Resultsmentioning

confidence: 91%

Regeneration effect of visible light‐curing furfuryl alginate compound by release of epidermal growth factor for wound healing application

Heo

Lee

Kim

et al. 2013

J of Applied Polymer Sci

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A visible light‐curable polysaccharide conjugate was prepared and was included with epidermal growth factor (EGF) for wound healing application. Alginate was modified with furfurylamine, and the furfuryl alginate (F‐alginate) was mixed with Rose Bengal for visible light reactivity. The introduction of furfuryl group was confirmed by 1H‐NMR and UV/vis spectroscopy. Visible light‐induced crosslinking was evaluated by micropatterning and weight measurement. Swelling ratio was also determined. To verify its applicability in wound healing applications, EGF was included in the system of F‐alginate and Rose Bengal. After the confirmation of no cytotoxicity of F‐alginate and murine EGF release from the system, cell proliferation, antibacterial activity, and animal test were performed on the system. In conclusion, it was demonstrated that the system was useful for wound healing. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40113.

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“…27 This is not new since methylated FA oligomers have been isolated and characterized previously. 28,29 The signals between 1.50 and 3.50 ppm indicate the presence of other aliphatic protons. 30 The likely origin of the unassigned aliphatic signals is the opening of some furan rings.…”

Section: Morphology and Characterization Of Pfa Nanospheresmentioning

confidence: 99%

Poly(furfuryl alcohol) nanospheres: a facile synthesis approach based on confinement effect of polymer and a template for synthesis of metal oxide hollow nanospheres

Wang

et al. 2015

Bull Mater Sci

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This paper describes a facile hydrothermal approach to the large-scale synthesis of well-dispersed poly(furfuryl alcohol) (PFA) nanospheres with an average diameter of 350 nm in the presence of poly(vinyl pyrrolidone) (PVP). Scanning electron microscopy and transmission electron microscopy studies showed that different morphologies of PFA could be obtained by adjusting the ratio of PVP and furfuryl alcohol (FA). As a whole, the results demonstrate that PVP plays a key role in controlling the polymerization process of FA. The confinement effect of PVP is proposed to explain the formation process of PFA nanospheres. Furthermore, the as-prepared PFA nanospheres have a functional surface that allow them to act as an ideal template for fabricating metal oxide hollow nanospheres.

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The chemistry of furfuryl alcohol resins

Cited by 95 publications

References 10 publications

Tailoring the 3D Structure of Pd Nanocatalysts Supported on Mesoporous Carbon for Furfural Hydrogenation

Tailoring the 3D Structure of Pd Nanocatalysts Supported on Mesoporous Carbon for Furfural Hydrogenation

Regeneration effect of visible light‐curing furfuryl alginate compound by release of epidermal growth factor for wound healing application

Poly(furfuryl alcohol) nanospheres: a facile synthesis approach based on confinement effect of polymer and a template for synthesis of metal oxide hollow nanospheres

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