Lignite can be upgraded by using
microwave irradiation (MI), which
may change physical and chemical properties of the coal, affecting
its combustion characteristics. In this work, MI was used to upgrade
coal samples, and the changes in combustion characteristics of the
upgraded coal samples were analyzed by thermogravimetric analysis
(TGA) and surface temperature measurement. The method of sequential
extraction was employed to investigate the changes of various Na classes
in different coal samples, and laser-induced breakdown spectroscopy
was then used to measure the temporal sodium release during combustion
of the different coal samples. Results show that the MI process significantly
reduces the moisture concentration, thereby increasing the carbon
content and calorific value of the coal. The decrease of the oxygen–carbon
atomic ratio indicates an improvement of the coal rank. The TGA shows
that the upgrading process will delay the combustion process toward
higher temperatures. The comprehensive combustion parameter calculated
from the TGA shows the combustion performance of upgraded coal samples
became worse, which is also seconded by the measured surface temperatures.
MI produces interconversion among different sodium classes, particularly
between NH4Ac-soluble sodium and water-soluble sodium.
The sodium release characteristics are similar to the surface temperature
profiles, indicating that, despite the MI process, sodium release
is predominantly controlled by the combustion process. However, the
MI process is found to increase both the mass fraction of sodium in
coal samples and the amount of sodium release during the combustion
process.