The Crystal Structure of SbPO4.

Synthesis and Structures of a Layered and a Tubular Antimony(III) Phosphonate

“…In all three phosphonate systems, the introduction of a small cation favors a tubular material over a layered material. The small cation could also be necessary for formation of the [SbO E] spiro-5 units: the unit is found in NaSb O (PO ) , while the few reported antimony(III) phosphates/phosphonates/phosphites synthesized hydrothermally in the absence of cations (6,41,42) contain only even-membered rings (Sb P , Sb P , Sb P , 2 ) or edge-sharing odd-membered rings. Certainly, more Sb P rings and [SbO E]-based spiro-5 motifs will be found, though it remains to be seen if the presence of these units will lead to nanoporous open antimony(III) phosphate/phosphonate frameworks.…”

Reaction of SbPO4 with lithium in non-aqueous electrochemical cells: preliminary study and evaluation of its electrochemical performance in anodes for lithium ion batteries

“…Infinite sheets of SbPO 4 composition are then stacked in the direction of the a-axis [15]. This compound has the ability to intercalate various organic molecules while retaining its layered framework [16].…”

A Novel Framework Antimony (III) Phosphate: Synthesis and Structure of NaSb3O2(PO4)2

“…The bond lengths (Table 2) and angles in the [SbO ] and [SbO ] units are comparable to those in antimony (III) phosphates (9,10) and #uoride phosphates (20); the formation of [SbO ] units occurs only when three-coordinated O atoms, of which there are four, are involved (Fig. 1).…”