The crystal structure of zinc guanidinium sulfate

Synthesis, crystal structure, phase transition and thermal behaviour of a new dabcodiium hexaaquanickel(II) bis(sulphate), (C6H14N2)[Ni(H2O)6](SO4)2

“…A great interest has been shown in some double sulphates of trivalent metal with monovalent aliphatic ammonium cations because of their ferroelastic and ferroelectric properties [1][2][3][4][5]. So far, there are few data on double sulphates of divalent metal cation with mono or divalent organic cations [6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21]. In order to expand the emergent chemistry of double sulphates of transition metal with diamine and to obtain crystals exhibiting ferroelectric or ferroelastic properties, a new compound using 1,4-diazabicyclo [2.2.2]octane (hereafter referred to as dabcodiium) as a template and nickel as transition metal has been synthesised.…”

Growth and characterization of new semiorganic nonlinear optical zinc guanidinium sulfate single crystal

“…The sulfate ion on a two-fold axis has one pair of oxygen atoms coordinated to zinc ions, resulting in an S-O bond. The guanidinium ions are not involved in metal coordination; rather they form hydrogen bonds with sulfate groups [7]. ZGuS crystal was subjected to powder X-ray diffraction analysis using Reich-Seifert diffractometer with CuKa (l ¼ 1.5418 Å ) radiation.…”

3-D Hydrogen bonded networks of three organically templated cadmium sulfates. Dehydration reactions and crystallization behavior

“…A wide range of structures have been obtained, 1-D [12,13], 2-D [11,[14][15][16][17], and 3-D [11,[17][18][19], all consisting of inorganic frameworks built from strong metal-oxygen bonds. Supramolecular networks of hexaaquametal sulfates including amine groups have been much less investigated although the crystal engineering of supramolecular compounds is known to favor electric and magnetic properties and compounds with hydrogen-bonded structures can lead to interesting ONL properties.…”