The  decays of the two 82 As isomers have been investigated by and ␥-ray spectroscopy to elucidate details in the population of levels in 82 Se, and to determine the ground state energy of 82 As. The relative positions of the -decaying states have been determined for the first time. The spin of the ground state, previously assumed to be 1 + , is proposed to be 2 − , in agreement with systematics. The new data confirm many previously known features of the 82 Se level scheme, but has also led to significant corrections. During the course of this work, the first information on absolute ␥-ray intensities in the decay of 82 Ge was obtained.