“…These results, however, were never unequivocally confirmed during bottle incubation experiments of ambient Southern Ocean water subjected to enrichments of Zn (Scharek et al, 1997;Coale et al, 2003;Ellwood, 2004) or Mn (Martin et al, 1990a, Buma et al, 1991Scharek et al, 1997;Sedwick et al, 2000). In retrospect, the lack of evidence (Martin et al, 1990b;Coale et al, 2005;Ellwood, 2008;Croot et al, 2011). Dissolved Zn and Si are generally strongly correlated in the Southern Ocean, even though a physiological mechanism connecting Si and Zn uptake in marine diatoms remains elusive (Ellwood, 2008;Croot et al, 2011).…”