The effect of electric-field-induced alignment on the electrical mobility of fractal aggregates

Abstract

We study the effects of electric field strength on the mobility of soot-like fractal aggregates (fractal dimension of 1.78). The probability distribution for the particle orientation is governed by the ratio of the interaction energy between the electric field and the induced dipole in the particle to the energy associated with Brownian forces in the surrounding medium. We use our extended Kirkwood-Riseman method to calculate the friction tensor for aggregates of up to 2000 spheres, with primary sphere sizes in the transition and near-free molecule regimes. Our results for electrical mobility versus field strength are in good agreement with published experimental data for soot, which show an increase in mobility on the order of 8% from random to aligned orientations. Our calculations show that particles become aligned at decreasing field strength as particle size increases because particle polarizability increases with volume. Large aggregates are at least partially aligned at field strengths below 1000 V/cm, though a small change in mobility means that alignment is not an issue in many practical applications. However, improved differential mobility analyzers would be required to take advantage of small changes in mobility to provide shape characterization.

Review—Reorientation of Polymers in an Applied Electric Field for Electrochemical Sensors

“…1b; however, this is also dependent on the anisotropic polarizability of the monomer. [46][47][48] A larger AEF can result in normal, or perpendicular, orientation. 45,49 Further, the interaction of block-copolymer nanostructures and AEFs can result in spacing of molecules.…”