The effect of hard block content on the orientation and mechanical properties of olefin block copolymer films as obtainedviamelt stretching

Abstract

In this study, the orientation, structure and mechanical performance of a series of uniaxially oriented films based on olefin block copolymers (OBC) have been investigated in terms of the differences in hard block content and draw ratio (DR). Three OBCs with different hard block contents of 35 wt%, 25 wt% and 12 wt% were used. For un-stretched films, a change from close-packed spherulites into tiny crystallites is observed with decreasing hard block content, accompanied by an almost linear decrease in crystallinity.However, the change in mechanical properties does not follow the same path, with obviously higher tensile strength and modulus for OBC-35, but a lower and almost the same tensile strength and modulus for OBC-25 and OBC-12, in spite of the big difference in hard block content and crystallinity between them. For melt-stretched films, the degree of orientation of the amorphous phase is almost the same and slightly increases with the increase in the draw ratio for the three OBCs, disregarding their hard block contents. Crystalline orientation and shish content are much higher for OBC-35, and an obvious increase is seen as the draw ratio increases from 4.95 to 8, corresponding to the sharp increase in Young's modulus and stress. For OBC-25 and OBC-12, similar crystalline orientation and shish content are seen, which increase linearly with draw ratio and are consistent with the linear increase in modulus and stress as the draw ratio increases. Our study demonstrates the importance of the hard block content of OBC to determine the mechanical properties and the response to external stretching. A critical hard block content exists (in this case 35 wt%), above which a strong network is constructed by the hard block crystalline phase, resulting in a higher tensile strength and modulus. This strong network is destroyed as the draw ratio reaches a certain value (herein, 4.95 to 8), leading to an obvious increase in crystalline orientation, as well as a sharp increase in tensile strength and modulus. When the hard block is below the critical content (herein, 25 wt% and 12 wt%), the network constructed by the hard block is weak and less dependent on its content.

Clarification of the effects of topological isomers on the mechanical strength of comb polyurethane

“…The control of these mechanical properties allows for industrial application in a wide range of fields. 10,11 Incidentally, amorphous polymers without a strong intermolecular interaction do not usually exhibit a significant change in the mechanical properties on stress-strain curves due to the branched topology. The longchain branch structure of the polycarbonate, which is a typical amorphous polymer, shows almost the same stress-strain curve as the linear structure.…”

The Influence of DMDBS on Crystallization Behavior and Crystalline Morphology of Weakly-Phase-Separated Olefin Block Copolymer

“…Figure 1a1 shows that there was no background information, since no crystallization occurred. After the temperature dropped to 116 °C, the hard segments of OBC started to crystallize [2]. Figure 1a2 shows typical spherulites of OBC after having been isothermally crystallized at 116 °C for 10 min.…”

“…Due to so-called chain shuttling technology, olefin block copolymer (OBC) has been recently synthesized by Dow Chemical Company, and commercialized as a thermoplastic elastomer [1,2,3,4]. As shown in Scheme 1, during the chain growth process, a chain shuttling agent was used to either activate or inactivate the branch incorporation of 1-octene into the chains, resulting in a multiblock copolymer of semicrystalline polyethylene (PE) hard segments, alternating with amorphous soft segments with short branches [5,6].…”

Toward Olefin Multiblock Copolymers with Tailored Properties: A Molecular Perspective

“…∆ values reflect such a tendency, the quantity of HB% determines the temperature at which mesophase separation takes place. [23][24][25][26][27][28] The molecular characteristics discussed in this section, referred to as property-related characteristics of OBCs, can appropriately provide one with a deeper understanding of structure-property relationship for tailoring OBCs. This will be discussed in more detail in the following sections.…”

“…There is evidence that rheological behavior is sensitive to mesophase separation. [24][25][26][27][28] In addition, LES SOFT and LES HARD can also contribute to the crystallization behavior of OBCs. [29][30][31][32][33][34][35] Accordingly, the above-discussed characteristics are correctly defined as property-related molecular variables of OBCs.…”