The extraction of constitutive parameters of metamaterials, i.e., electrical permittivity (ε) and magnetic permeability (μ), is quite challenging. Usually, two techniques are used for this purpose, namely, the Nicolson‐Ross‐Weir technique and the dispersive models technique (Lorentz and Drude). However, these techniques fail to produce accurate results when the operating frequency is near the cell resonance frequency. In this article, an improved transition layer‐based homogenization procedure is proposed where the metamaterial cell is homogenized as a Drude–Lorentz multilayer slab. This assumption considerably improves the scattering parameters approach, as demonstrated for a metamaterial slab with a thickness of three Omega cells. In addition, the proposed technique is more suitable for implementation in finite difference time domain (FDTD) methods. © 2016 Wiley Periodicals, Inc. Microwave Opt Technol Lett 58:1490–1494, 2016