We present here a novel construction of Au/PPy-MWCNTs/TiO2/Al2O3/p-Si/Al which was not given in a lecture earlier. We synthesized this construction for request in manufactured electronic devices, sensors, supercapacitors, diodes, and high-energy storage devices and successfully tuned the dielectric constant ɛ' and dielectric loss tangent tan δ by variable frequency, temperature, and voltage. At high frequency (2×107 Hz), the dielectric constant ɛ' and dielectric loss tangent tan δ have positive and negative values from (250 to – 3500) and (-2 to 8), respectively; however at all frequencies (107, 106, 105) Hz, the ɛ' has high positive values (1000, 3500, 10000), but tan δ has low values (2.6, 1.8, 4.5). At frequencies of 103 and 102 Hz, the ɛ' and tanδ have positive and negative values, while at a frequency of 10 Hz, the ɛ' and tan δ have negative values only. The values of ɛ' with lnf at all voltages and temperatures have negative values at high and low frequencies. In mid frequencies, the ɛ' have positive values. Also, the Col-Col diagram and the current conduction mechanism of this construction Au/PPy-MWCNTs/TiO2/Al2O3/p-Si/Al were studied.