“…In the Ga-rich samples, all modes are close to those of bulk GaN (LO) = 733 cm −1 , TO = 566 cm −1 , 18,28 and approach the frequency values of bulk InN, which are A1(LO) = 585 cm −1 and TO = 455.7 cm −1 . 29 Figure 3b shows that this feature is also shifted to lower frequencies upon increasing the indium content, 28,30 in agreement with the PL and XRD results.…”