2018
DOI: 10.1107/s2053229617016886
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The ephemeral dihydrate of sulfanilic acid

Abstract: Evaporation of an aqueous solution of sulfanilic acid (systematic name: 4-aminobenzene-1-sulfonic acid) at 273 K affords a crystalline dihydrate, CHNOS·2HO. The organic molecule exists as a zwitterion; two zwitterions are aligned in an antiparallel fashion about a crystallographic centre of inversion. They interact directly via two N-H...O hydrogen bonds between the ammonium group of one zwitterion and the sulfonate group of its symmetry-related counterpart, and their aromatic rings are π-stacked, with an inte… Show more

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Cited by 4 publications
(1 citation statement)
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“…They exhibit regular values of bond lengths and angles in comparison with ordinary organic molecules . These geometric parameters also well correspond to those found in the structures of starting compounds and/or their hydrates (taurine, , sulfanilic acid, orthanilic acid, metanilic acid, 3-pyridinesulfonic acid, and hydroxy­(quinolinium-2-yl)­methanesulfonate). The O–O bond distances lie within the normal range for solvent H 2 O 2 molecules (1.442(7)–1.470(2) Å) .…”
Section: Resultssupporting
confidence: 77%
“…They exhibit regular values of bond lengths and angles in comparison with ordinary organic molecules . These geometric parameters also well correspond to those found in the structures of starting compounds and/or their hydrates (taurine, , sulfanilic acid, orthanilic acid, metanilic acid, 3-pyridinesulfonic acid, and hydroxy­(quinolinium-2-yl)­methanesulfonate). The O–O bond distances lie within the normal range for solvent H 2 O 2 molecules (1.442(7)–1.470(2) Å) .…”
Section: Resultssupporting
confidence: 77%