We give a uniform, Lie-theoretic mirror symmetry construction for the Frobenius manifolds defined by on the orbit spaces of extended affine Weyl groups, including exceptional Dynkin types. The B-model mirror is given by a one-dimensional Landau-Ginzburg superpotential constructed from a suitable degeneration of the family of spectral curves of the affine relativistic Toda chain for the corresponding affine Poisson-Lie group. As applications of our mirror theorem we give closed-form expressions for the flat coordinates of the Saito metric and the Frobenius prepotentials in all Dynkin types, compute the topological degree of the Lyashko-Looijenga mapping for certain higher genus Hurwitz space strata, and construct hydrodynamic bihamiltonian hierarchies (in both Lax-Sato and Hamiltonian form) that are root-theoretic generalisations of the long-wave limit of the extended Toda hierarchy.