4d electron excitations have been investigated in several rare-earth metals (Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb) by means of electron energy losses of a high energy (75 keV) electron beam. Experiments were made with a transmission electron microscope modified by the adjunction of a Castaing-Henry dispersive system. The results of the measurements lying in the energy range between 120 and 190 eV agree rather well with X-ray photoabsorption spectra and oscillator strengths calculated in an atomic model.