1995
DOI: 10.1039/c39950000679
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The first solid state paramagnetic 1,2,3,5-dithiadiazolyl radical; X-ray crystal structure of [p-NCC6F4CNSSN]?

Abstract: The solid state structure of the fluorinated If2,3,. is reported; it is the first dithiadiazolyl radical t o retain its paramagnetic character in the solid state.

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Cited by 81 publications
(62 citation statements)
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“…This compound is polymorph. The a-phase of 1 orders as an antiferromagnet at 8 K [9]. This high temperature indicates that the magnetic interactions are much stronger than in previously reported open-shell N-and O-based radicals.…”
Section: Introductionmentioning
confidence: 63%
“…This compound is polymorph. The a-phase of 1 orders as an antiferromagnet at 8 K [9]. This high temperature indicates that the magnetic interactions are much stronger than in previously reported open-shell N-and O-based radicals.…”
Section: Introductionmentioning
confidence: 63%
“…[127,128] It also provides another example of concomitant crystallization by sublimation. Large black blocks of the a phase may be obtained pure by very rapid vacuum sublimation at 120 8C and 10 À2 Torr.…”
Section: Free Radicals By Sublimationmentioning
confidence: 97%
“…, 1, which is polymorphic [9,10]. The a-phase orders antiferromagnetically at 8 K [9], whereas preliminary magnetic measurements of the b-phase, 1b, indicate the onset of a spontaneous magnetic moment below 36 K [10], an exceptionally high temperature for a purely organic free radical.…”
mentioning
confidence: 99%