The scientist Fedor Ivanovich Stein and the artist Emelian Karneev, members of the Russian Expedition, in Sydney in March 1820, had a brief journey into the Blue Mountains, in company with the explorer William Lawson and the botanist Allan Cunningham. Impressed with the mountain scenery Stein named a few localities for European savants, some of the earliest so named in Australia. These names never became recognised. Karneev's sketches, some of the first made of the Wentworth Falls locality, are apparently lost. Stein's report of the journey, a mixture of fact and scientific oddities, is presented in English for the first time.