We combine observations from the Atacama Large Millimeter/submillimeter Array (ALMA) and the NOrthern Extended Millimeter Array (NOEMA) to assess the redshift and to study the star formation conditions in AzTEC2: one of the brightest sub-millimeter galaxies (SMGs) in the COSMOS field (S 1.1mm = 10.5 ± 1.4 mJy). Our high-resolution observations confirm that AzTEC2 splits into two components (namely AzTEC2-A and AzTEC2-B) for which we detect [C II] and 12 CO(5→4) line emission, implying a redshift of 4.626±0.001 (4.633±0.001) for AzTEC2-A (AzTEC2-B) and ruling out previous associations with a galaxy at z ∼ 1. We use the 12 CO(5→4) line emission and adopt typical SMG-like gas excitation conditions to estimate the molecular gas mass, which is M gas (α CO /2.5) = 2.1 ± 0.4 × 10 11 M for AzTEC2-A, and a factor four lower for AzTEC2-B. With the infrared-derived star formation rate of AzTEC2-A (1920 ± 100 M yr −1 ) and AzTEC2-B (710 ± 35 M yr −1 ), they both will consume their current gas reservoir within (30−200) Myr. We find evidence of a rotation-dominated [C II] disk in AzTEC2-A, with a de-projected rotational velocity of v rot (i = 39 • ) = 660 ± 130 km s −1 , velocity dispersion 100 km s −1 , and dynamical mass of M dyn (i = 39 • ) = 2.6 +1.2 −0.9 × 10 11 M . We propose that an elevated gas accretion rate from the cosmic web might be the main driver of the intense levels of star formation in AzTEC2-A, which might be further enhanced by gravitational torques induced by its minor companion (AzTEC2-B). These results strengthen the picture whereby the population of single-dish selected SMGs is rather heterogeneous, including a population of pairs of massive, highly-active galaxies in a pre-coalescence phase.