The Hybrid Organic–Inorganic Assemblies Based on Monocapped Trivacant Keggin Arsenatomolybdate and CuI-Organic Units

Zhao, Zhifeng; Su, Zhanhua; Zhao, Wenqi; Gao, Wei; Cong, Bowen; Zhou, Baibin

doi:10.1007/s10876-016-1022-y

Cited by 4 publications

(2 citation statements)

References 32 publications

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“…As it is known that POMs have better electrocatalytic activity . Figure c and d shows the redox curves for electrocatalytic reduction of NO 2 – at 1 and 2 ‐CPE in 1 m H 2 SO 4 solution, respectively, which proves that the two pairs of redox peak currents on electrocatalytic curve gradually increase, while the oxidation peak currents gradually decrease when nitrite concentration increase from 0–30 mM, which indicates that 1 and 2 display obvious electrocatalytic activity for the reduction of NO 2 – .…”

Section: Resultsmentioning

confidence: 67%

Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [H_xAs₂Mo₆O₂₆]^(6–x)– Clusters

Zhao

Cong

et al. 2017

Zeitschrift anorg allge chemie

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The arsenomolybdates [H2As2Mo6O26(H2O)]·(H2biyb)2·2H2O (1) and [H3As2Mo6O26]·(H3pt)2 (2) [biyb = 1,4‐bis(imidazol‐1‐ylmethyl)benzene, pt = 4′‐(3′′‐pyridyl)‐2,3′:6′3′′‐terpyridine] were synthesized via hydrothermal method. The structures of the compounds were characterized by single‐crystal X‐ray diffraction analyses, elemental analyses, IR spectroscopy, and TG analysis. Compounds 1 and 2 exhibit two isomeric forms of [HxAs2Mo6O26](6–x)–. The structure of 1 is constructed from the B‐type [H2As2Mo6O26(H2O)]4– polyanions and free biyb ligands via weak interactions to form 3D supramolecular framework with a {3·4·53·6}{3·43·52}{3·5·6}2{3·52}2 topology structure. In compound 2, the A‐type [H3As2Mo6O26]3– clusters are surrounded by pt ligands through hydrogen bond interactions forming 3D supramolecular framework with a {43·63}2{46·66·83} topology structure. The electrochemical behaviors, electrocatalytic and photocatalytic activities of 1 and 2 are detected.

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Section: Resultsmentioning

confidence: 67%

Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [H_xAs₂Mo₆O₂₆]^(6–x)– Clusters

Zhao

Cong

et al. 2017

Zeitschrift anorg allge chemie

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“…After UV light irradiation of (H 2 bimyb) 3 (As 2 Mo 18 O 62 ) for 70 min, the photocatalytic decomposition rate is 95.82% [49]. It is reported that the conversion rate of MB is 94.6% when adding compound [Cu(imi) 2 ] 5 Na[(AsO 4 )Mo 9 O 27 (AsO 3 )]Á5H 2 O as the photocatalyst after 105 min[50]. {Cu(2,2 0 -bpy)} 2 {H 2 As 2 Mo 2 O 14 } as photocatalyst was investigated via the photodecomposition of MB under UV light irradiation and the same conditions.…”

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confidence: 99%

Arsenomolybdates for Photocatalytic Degradation of Organic Dyes

Zhao¹

2021

Photophysics, Photochemical and Substitution Reactions - Recent Advances

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Polyoxometalates (POMs) have fascinating structures and promising properties. The arsenomolybdates, as an important branch of POMs, are outstanding photocatalysts for organic dyes. In this work, we selected organic dyes to evaluate the photocatalytic activity of arsenomolybdates under UV light, containing compared with photocatalytic activity of different structural arsenomolybdates, stability, and the photocatalytic reaction mechanism of arsenomolybdates as photocatalyst. The arsenomolybdates may be used to as environmental photocatalysts for the degrading of organic dyes and solving the problem of environmental pollution.

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The New Arsenomolybdate Based on Monocapped Trivacant Keggin {H4AsIIIAsVMo9O34} Cluster and Cu–abi Complex: Synthesis, Structure, Photoluminescence and Catalysis Properties

Zhao

Cong

et al. 2018

J Clust Sci

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The Hybrid Organic–Inorganic Assemblies Based on Monocapped Trivacant Keggin Arsenatomolybdate and CuI-Organic Units

Cited by 4 publications

References 32 publications

Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [H_xAs₂Mo₆O₂₆]^(6–x)– Clusters

Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [H_xAs₂Mo₆O₂₆]^(6–x)– Clusters

Arsenomolybdates for Photocatalytic Degradation of Organic Dyes

The New Arsenomolybdate Based on Monocapped Trivacant Keggin {H4AsIIIAsVMo9O34} Cluster and Cu–abi Complex: Synthesis, Structure, Photoluminescence and Catalysis Properties

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The Hybrid Organic–Inorganic Assemblies Based on Monocapped Trivacant Keggin Arsenatomolybdate and CuI-Organic Units

Cited by 4 publications

References 32 publications

Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [HxAs2Mo6O26](6–x)– Clusters

Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [HxAs2Mo6O26](6–x)– Clusters

Arsenomolybdates for Photocatalytic Degradation of Organic Dyes

The New Arsenomolybdate Based on Monocapped Trivacant Keggin {H4AsIIIAsVMo9O34} Cluster and Cu–abi Complex: Synthesis, Structure, Photoluminescence and Catalysis Properties

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Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [H_xAs₂Mo₆O₂₆]^(6–x)– Clusters

Organic‐Inorganic Hybrid Supramolecular Assemblies Based on Isomers [H_xAs₂Mo₆O₂₆]^(6–x)– Clusters