The
goal of this research was to determine the feasibility of employing
the catalytic steam reforming of biogas to increase its energy content
by converting the methane it contains into a hydrogen-rich syngas
mixture and using this reformate product intermixed with raw biogas
in a lean-burn gas engine in order to enhance combustion stability
and to reduce NOX emissions. The field-testing component
of the project involved catalytically reforming a side stream of biomethane
from a landfill gas collection system at a California landfill via
a waste energy chemical recuperation process, in which waste heat
from a gas engine was used to promote the reforming reaction of biogas.
In the study, the total flow of raw biogas diverted to the engine
remained constant. A fraction of that biogas was, however, separated
and directed to the aforementioned catalytic reactor. The reformer
exit stream was then dried, blended with the remaining biogas, and
burned in an internal combustion engine to produce electricity. When
operating on the blended biogas mixture, combustion stability was
enhanced, and the engine ran smoothly at the full speed of 3600 rpm
with a 60 Hz output frequency. On the other hand, when burning raw
biogas without any reformate gas blended, the test engine ran poorly,
sputtering and never reaching 3600 rpm. Also, when operating at various
loads under fuel-lean (excess-air) conditions, NOX emissions
were significantly reduced when compared to the engine operating on
propane under the same load conditions. Similar comparative testing
could not be performed on raw landfill gas alone because the engine
would not operate at full speed, as noted above. The research presented
here has validated the technical and economic feasibility of using
reforming products during biogas combustion in a lean-burn gas engine
in order to reduce NOX emissions and to enhance combustion
stability. This, in our opinion, is an important contribution to the
scientific/technical literature and a significant advance for the
field of biogas utilization.