2012
DOI: 10.1088/0004-637x/749/1/76
|View full text |Cite
|
Sign up to set email alerts
|

THEv= 3 ← 0S(0)-S(3) ELECTRIC QUADRUPOLE TRANSITIONS OF H2NEAR 0.8 μm

Abstract: The very weak S(0)-S(3) electric quadrupole transitions of the second overtone band of molecular hydrogen have been recorded in the laboratory by continuous-wave cavity ring-down spectroscopy near 0.8 μm. The ultrahigh sensitivity of the spectrometer (α min ∼ 1 × 10 −10 cm −1 ) allows us to detect the considered transitions at a relatively low sample pressure (50-750 torr). The line positions, intensity, and pressure-shift coefficients are derived from a fit of the line shape using a Galatry profile. Compared … Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

2
30
0

Year Published

2013
2013
2020
2020

Publication Types

Select...
8

Relationship

0
8

Authors

Journals

citations
Cited by 42 publications
(32 citation statements)
references
References 26 publications
2
30
0
Order By: Relevance
“…Some overtone transition frequencies of molecular hydrogen have been determined via single-photon infrared absorptions, with the most recent investigations employing cavity-ringdown (CRDS) techniques [41][42][43]. Despite the sensitivity of CRDS, the extremely weak quadrupole transitions necessitate high-pressure samples subject to pressure shifts in addition to Doppler-broadening.…”
Section: Precision Measurements In Moleculesmentioning
confidence: 99%
See 1 more Smart Citation
“…Some overtone transition frequencies of molecular hydrogen have been determined via single-photon infrared absorptions, with the most recent investigations employing cavity-ringdown (CRDS) techniques [41][42][43]. Despite the sensitivity of CRDS, the extremely weak quadrupole transitions necessitate high-pressure samples subject to pressure shifts in addition to Doppler-broadening.…”
Section: Precision Measurements In Moleculesmentioning
confidence: 99%
“…v = 0 to v = 2, 3) of H 2 and D 2 . The results from recent CRDS studies on the overtone quadrupole transitions of H 2 [41,42] and D 2 [40,43] can be used to extract constraints. The overtone transitions of H 2 and D 2 have intrinsically higher sensitivity of the transitions in comparison to the fundamental ground tone as shown in Fig.…”
Section: B Overtone Vibrations In Neutral Hydrogenmentioning
confidence: 99%
“…For CH 4 and CH 3 D, we compute the opacity using the spectroscopic line parameters from the GEISA 2011 database (Jacquinet-Husson et al, 2008). For the H 2 quadrupolar lines we use the Campargue et al (2012); Hu et al (2012) intensities and positions, and the broadening parameters from Reuter and Sirota (1994). Finally, we take into account the H 2 collision-induced continuum due H 2 , He and CH 4 collision partners using the algorithm and numerical values of Borysow and Frommhold (1986) and Borysow et al (1985Borysow et al ( , 1988.…”
Section: Forward Radiative Transfer Modelmentioning
confidence: 99%
“…These calculations on the ground electronic quantum levels were tested in experiments measuring the dissociation limits of H 2 [23], D 2 [24], and HD [25]. Further, they were compared to the experimental values for the fundamental vibrational splitting in both H 2 and hydrogen isotopomers [26,27], to a measurement of the first overtone in H 2 [28,30] and D 2 [29], a measurement of the second overtone in H 2 [31,32], and measurements of highly excited rotational levels in H 2 [33]. The results from a variety of experimental precision measurements on both the ionic and neutral hydrogen molecules are generally in excellent agreement with the QED calculations, within combined uncertainty limits from theory and experiment.…”
Section: Introductionmentioning
confidence: 99%