The Impact of Domains on the Dielectric and Electromechanical Properties of Ferroelectric Thin Films

Abstract

In ferroelectric thin films for capacitive and piezoelectric applications, it is important to understand which mechanisms contribute to the observed dielectric constant and piezoelectricity. In soft PZT (PbZr1−xTixO3) ceramics, over half the room temperature response is associated with domain wall contributions to the properties. However, recent studies on bulk ceramics have demonstrated that the number of domain variants within grains, and the mobility of the twin walls depend on the grain size. This leads to a degradation in the dielectric and piezoelectric properties for grain sizes below a micron. This has significant consequences for thin films since a lateral grain size of 1 μm is often the upper limit on the observed grain size. In addition, since the pertinent domain walls are ferroelastic, the stress imposed on the film by the substrate could also clamp the piezoelectric response. To investigate these factors, controlled stress levels were imposed on PZT films of different thickness while the dielectric and electromechanical properties were measured. It was found that for undoped sol-gel PZT 40/60, 52/48, and 60/40 thin films under a micron in thickness, the extrinsic contributions to the dielectric and electromechanical properties make very modest contributions to the film response. No significant enhancement in the properties was observed even when the film was brought through the zero global stress condition. Comparable results were obtained from laser ablated films grown from hard and soft PZT targets. Finally, little twin wall mobility was observed in AFM experiments. The consequences of this in terms of the achievable properties in PZT films will be presented. Work on circumventing these limitations via utilization of antiferroelectric phase switching films and relaxor ferroelectric single crystal films will also be discussed.

Orientation dependence of fatigue behavior in relaxor ferroelectric–PbTiO3 thin films

“…Submicron grain sizes and/or residual stresses are believed to clamp the non-180°domain walls and thus limit their contribution to the film response. 28 As shown in Fig. 7, there are four possible polar directions in the pseudocubic perovskite cell which have a component of the polarization along the ϩZ direction ͑i.e., directed out of the plane of the film͒.…”