Abstract. The purpose of this research was to study the combustion characteristics of palm kernel shell (PKS) mixed with crude glycerol. Initial supplied air and ratios of glycerol were varied for best combustion to obtain high temperature, high combustion rate and minimum emission. PKS is mixed with molasses and crude glycerol at 3 different ratios by mass i.e. 90:10:0, 85:10:5, 80:10:10 (PKS: molasses: crude glycerol). Mixed material was compressed at 10 MPa in a designed hydraulic briquettizer. Then the briquette was burnt with different supplied airs corresponding to 600%, 750%, 900% and 1050% theoretical air. The results show that when crude glycerol and supplied air were increased, the temperatures and rates of combustion increased to a maximum value and dropped. For exhaust gasses analysis, Carbon monoxide (CO), Nitrogen dioxide (NO 2 ), Sulfur dioxide (SO 2 ) and Acrolein gas were all within Standards. Therefore, it can be concluded that PKS mixed with crude glycerol at 85:10:5 and theoretical air of 900% provide the best combustion and is recommended for use as briquette fuel.