The influence of an electric field on the radiolysis of gaseous cyclohexane

Milon, Hubert; Gäumann, Tino

doi:10.1016/0020-7055(75)90080-7

International Journal for Radiation Physics and Chemistry

1975

DOI: 10.1016/0020-7055(75)90080-7

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The influence of an electric field on the radiolysis of gaseous cyclohexane

Hubert Milon

Tino Gäumann

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1979

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Cited by 5 publications

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Disproportionation‐to‐combination ratios for cyclohexyl‐h₁₁ and ‐d₁₁ radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures

Fujisaki

Gäumann

1979

Int J of Chemical Kinetics

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In the radiolysis of water vapor containing small concentrations of cyclohexane, the principal products which account for about 98% of all end products are found to be hydrogen, cyclohexene, and bicyclohexyl. Cyclohexene and bicyclohexyl yields were determined over a range of temperatures (70-200°C), total pressures (50-2400 torr), and total doses (0.15-2.0 Mrad). The disproportionation-combination ratio k;/kP for c -C~H I I radicals could be determined as 0.56 f 0.01 from the ratio of cyclohexene to bicyclohexyl yield. By using c-CgD12, the ratio kflkf for c-CgDII radicals is found to be 0.38 f 0.01. Comparison of the reactivity pattern of CgHll and CgDll radicals leads to (k;/kF)/(kf/kF) = 1.47 f 0.02. The corresponding values for the reactions of c-C~H11 with c-CgD11 were also determined.

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Disproportionation‐to‐combination ratios for cyclohexyl‐h₁₁ and ‐d₁₁ radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures

Fujisaki

Gäumann

1979

Int J of Chemical Kinetics

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Self‐ and cross‐disproportionation‐to‐combination rations for cyclopentyl and cyclohexyl radicals and their deuterated analogues

Fujisaki

Gäumann

1982

Int J of Chemical Kinetics

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Effect of pressure on the γ-radiolysis of n-pentane in the gas phase

Lukac

1980

Radiation Physics and Chemistry (1977)

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The influence of an electric field on the radiolysis of gaseous cyclohexane

Cited by 5 publications

References 19 publications

Disproportionation‐to‐combination ratios for cyclohexyl‐h₁₁ and ‐d₁₁ radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures

Disproportionation‐to‐combination ratios for cyclohexyl‐h₁₁ and ‐d₁₁ radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures

Self‐ and cross‐disproportionation‐to‐combination rations for cyclopentyl and cyclohexyl radicals and their deuterated analogues

Effect of pressure on the γ-radiolysis of n-pentane in the gas phase

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The influence of an electric field on the radiolysis of gaseous cyclohexane

Cited by 5 publications

References 19 publications

Disproportionation‐to‐combination ratios for cyclohexyl‐h11 and ‐d11 radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures

Disproportionation‐to‐combination ratios for cyclohexyl‐h11 and ‐d11 radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures

Self‐ and cross‐disproportionation‐to‐combination rations for cyclopentyl and cyclohexyl radicals and their deuterated analogues

Effect of pressure on the γ-radiolysis of n-pentane in the gas phase

Contact Info

Product

Resources

About

Disproportionation‐to‐combination ratios for cyclohexyl‐h₁₁ and ‐d₁₁ radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures

Disproportionation‐to‐combination ratios for cyclohexyl‐h₁₁ and ‐d₁₁ radicals in the gas phase as determined by the radiolysis of water vapor–cyclohexane mixtures