The influence of base oil type on the rheological properties of ecological lubricating greases

Abstract

The article presents the results of research on the influence the type of base oil in lubricating compositions has on the rheological parameters of selected lubricants. Vegetable, mineral, and synthetic dispersion phases were used to produce lubricating greases. The modified amorphous silica was used as the dispersed phase. However, as a modifying additive was used a substance containing the antioxidants, corrosion inhibitors, and EP/AW additives. The experiments on rheological properties were carried out using a Physica MCR 101 rotational rheometer (manufactured by Anton Paar), equipped with a diffusion air bearing and connected to a pneumatic supply – an oil-free Jun-Air compressor and air drying block. The device is equipped with a Peltier system for temperature control in the range of –20°C to 200°C and an external thermostatic VISCOTHERM V2 system, working in the temperature range of –20°C to 200°C. The rheometer control and measurement data analysis were performed using Rheoplus software. The tests were carried out using a cone-plate measuring system with a shear rate range of 0.01–100 s-1 at 20°C for lubricating compositions prepared on various oil bases. To evaluate the value of rheological parameters, the results of tests of the dependence between shear stress and shear rate (flow curves) were used. For the theoretical determined on the flow curves, the following rheological models were used: Bingham, Herschel–Bulkley, Casson, and Tscheuschner. The values of the shear stress (yield point) in depending on the type of dispersion phase has changed. This proves that the use of a base oil with the appropriate functional properties does not weaken, but reinforces the spatial structure of a lubricating grease. It has an important meaning when selecting construction parameters when designing a central lubrication system with grease made from a vegetable oil base (Abyssinian oil). The rheological properties of the lubricating grease are influenced by the type of base oil and thickener, any additives in the grease, the production technology of the grease, and the conditions in which it is used. The tests revealed an important influence of the base oil on the rheological parameters that describe the behaviour of lubricating compositions subjected to stresses and strains in a lubricating system.

The Tribological and Rheological Properties of Vegetable Lubricating Grease Modified of TiO2 Nanoparticles

“…To the tribological tests was used the lubricating composition, which was prepared using the nontoxic ingredients, that are a dispersing and dispersed phase [48][49][50][51]. As a dispersing phase, the vegetable oil with very good physicochemical properties was used.…”

“…flow limit. The tests were carried out for lubricating compositions prepared on vegetable oil with different content of titanium dioxide [50,52,54].…”

Influence of Silicon Additives on Tribological and Rheological Test Results for Vegetable Lubricants

“… The chemical structure of Aerosil ( a ) and SEM micrograph of the microstructure of Aerosil (scale bar 4000×) ( b ) [ 43 , 44 ]. The numbers 3–8 are the number of groups of (Si–O–) and I–III are the numbers of Si–OH groups.…”

“…It is used as a rheological additive and as an excellent thickener, thixotrope and anti-sedimentation agent. Due to its polar nature, it is easily associated with oil molecules by van der Waals forces [ 43 , 44 ].…”

Formulation of Biogreases derived from Mahua and Karanja Oil

“…Biofuels are already gaining popularity throughout the world because of their advantages and advantages over traditional petroleum fuels and also a chance to reduce the dependency on conventional fuels(Casas-Godoy et al, 2020). Now, a parallel and comparable growth is expected for biogreases, which are simply produced from non-edible vegetable oils to serve as specialty products for applications of lubrication(Rafał Kozdrach, 2021). The idea of manufacturing biolubricants based on vegetable oils and converting them into biogreases has attracted many researchers to develop progression tools for commercial production of such novel products with similar physicochemical properties and tribiological characteristics (McGuire, 2014;Vafaei et al, 2021).…”