Abstract:In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984-2001 and 1992-2001) and surface water chemistry (1992)(1993)(1994)(1995)(1996)(1997)(1998)(1999)(2000)(2001) were determined in two of the most acid-sensitive regions of North America, i.e. concentrations at all sites, and decreasing trends in NO 3 , C B , and H C concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid-neutralizing capacity (ANC) increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO 4 2 trends, but it caused several significant non-flow-corrected trends in NO 3 and ANC to become non-significant, suggesting that trend results for flow-sensitive constituents are affected by flow-related climate variation. SO 4 2 concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation-surface water comparisons, reflecting a strong link between S emissions, precipitation SO 4 2 concentrations, and the processes that affect S cycling within these regions. NO 3 and H C concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation-surface water comparisons, indicating that variation in local-scale processes driven by factors such as climate are affecting trends in acid-base chemistry in these two regions.