The fourth industrial revolution offers new technologies to transform conventional supply chain solutions into cyber-physical supply chain ones. This transformation makes it possible to increase the efficiency, availability, quality, and cost-efficiency of the value-making chain, while the energy consumption and the GHG emission can be decreased. Within the frame of this chapter, the authors introduce the most important Industry 4.0 technologies and Internet of Things tools and demonstrate their potentials to update supply chain operations. This update of conventional operations can lead to greener and more sustainable purchasing, production, and distribution processes. The successful future of the green supply chain is based on a wide range of factors, like production management, logistics management, societal and regulatory environment. However, the Industry 4.0 technologies are expected to strongly influence the whole supply chain performance positively. This chapter aims to explore the potentials of Industry 4.0 technologies and the transformation of conventional supply chain solutions into cyber-physical systems, especially from a municipal waste collection point of view. The research findings can provide useful insights for supply chain experts, manufacturing, and service companies.