1966
DOI: 10.1021/ic50038a039
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The Lattice Energy of Sodium Tetrachloroaluminate and the Heat Formation of the Tetrachloroaluminate Ion

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Cited by 13 publications
(7 citation statements)
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“…larizabilities in Table II were used to calculate the interaction constants in the interaction force constant, Q, and the van der Waals sums.Sy (Table III), using procedures described previously. 24 The calculations were performed assuming the following self-consistent charge distributions and Cl atom positions: for Cs2GeCl6, Cs= 14-, Ge = 0.802+, Cl = 0.467-, x = 0.2302; for K2SnCl6,K = 14-, Sn = 1.0+, Cl = 0.50-, x =0.2415; for Rb2PbCl6, Rb = 14-, Pb = 0.8984-, Cl = 0.483-, x = 0.2452. Table IV summarizes the results.…”
Section: Resultsmentioning
confidence: 99%
“…larizabilities in Table II were used to calculate the interaction constants in the interaction force constant, Q, and the van der Waals sums.Sy (Table III), using procedures described previously. 24 The calculations were performed assuming the following self-consistent charge distributions and Cl atom positions: for Cs2GeCl6, Cs= 14-, Ge = 0.802+, Cl = 0.467-, x = 0.2302; for K2SnCl6,K = 14-, Sn = 1.0+, Cl = 0.50-, x =0.2415; for Rb2PbCl6, Rb = 14-, Pb = 0.8984-, Cl = 0.483-, x = 0.2452. Table IV summarizes the results.…”
Section: Resultsmentioning
confidence: 99%
“…Aluminum trichloride has been shown to form remarkably volatile vapor complexes with alkaline earth chlorides (20), 3d transition metal dichlorides (20), and representative 4f (neodymium) (21) and 5f (uranium) (22) chlorides. A driving force for these reactions is the strong affinity of the aluminum trichloride for the chloride ions in these rather ionic compounds, ^ -78 + 7 Kcal/mole (23). No in vestigations of the vapor phase above metal-metal chloridealuminum trichloride systems have been reported in the literature.…”
Section: Introductionmentioning
confidence: 99%
“…The existence of gaseous tellurium dichloride, the vapor of which has been described as red to dark brown (23,24,25) is well established. The vibrational fine structure of the band system which appears in the visible region has been analyzed several times with varying conclusions (29,30,31).…”
Section: Introductionmentioning
confidence: 99%
“…A driving force for these reactions is the strong affinity of the aluminum trichloride for the chloride ions in these rather ionic compounds, ^ -78 + 7 Kcal/mole (23). No in vestigations of the vapor phase above metal-metal chloridealuminum trichloride systems have been reported in the literature.…”
mentioning
confidence: 99%
“…The existence of gaseous tellurium dichloride, the vapor of which has been described as red to dark brown (23,24,25) is well established. The vibrational fine structure of the band system which appears in the visible region has been analyzed several times with varying conclusions (29,30,31).…”
mentioning
confidence: 99%