2011
DOI: 10.2343/geochemj.1.0132
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The matrix effect on 238U and 232Th measurements using pressed powder pellets by LA-ICP-MS

Abstract: plex and time-consuming preparation procedures, or use of a nuclear reactor. Recently, laser ablation (LA)-ICP-MS has been developed and applied to measure the radioisotope concentrations for small quantities of samples with little analytical preparation time (e.g.

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Cited by 7 publications
(3 citation statements)
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“…Non-matrix matched calibration with NIST SRM610-614 glasses fails for some elements. 45 Here, matrix-matched calibration was achieved by calculating average "bias factors" for each element that were derived from the analysis of pressed powder tablets of basalts BCR-2 and BIR-1. These factors were applied to rock types with broadly "similar" chemical matrix composition, for example basalt BHVO-2 and diorite DR-N. Fig.…”
Section: Accuracy Of Analytical Results For Some Geochemical Rock Crmsmentioning
confidence: 99%
See 1 more Smart Citation
“…Non-matrix matched calibration with NIST SRM610-614 glasses fails for some elements. 45 Here, matrix-matched calibration was achieved by calculating average "bias factors" for each element that were derived from the analysis of pressed powder tablets of basalts BCR-2 and BIR-1. These factors were applied to rock types with broadly "similar" chemical matrix composition, for example basalt BHVO-2 and diorite DR-N. Fig.…”
Section: Accuracy Of Analytical Results For Some Geochemical Rock Crmsmentioning
confidence: 99%
“…Arroyo et al 44 dry-ground soil and sediment samples for 20 minutes by means of a high power mill and obtained particles with an average grain size of d 50 < 10 mm. Ito and coworkers 45 picked up the concept of dry ne-grinding and studied matrix effects on 238 U and 232 Th related to the grain size and nonmatrix matched calibration. There is a consensus from these studies that small grain sizes <10 mm are a prerequisite for homogeneity and acceptable data quality obtainable with ablation spot sizes of 80-200 mm.…”
Section: Introductionmentioning
confidence: 99%
“…) using integrated signal intensities (Ito et al . ). The signals were collected from a laser pit of 40 μm diameter × 50 μm depth.…”
Section: Methodsmentioning
confidence: 97%