2017
DOI: 10.1016/j.molstruc.2017.01.010
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The new metal complex templated polyoxoborate(s) (POB(s)) structures. Synthesis, structural characterization, and hydrogen storage capacities

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Cited by 10 publications
(5 citation statements)
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“…The same behavior is entirely consistent with related hydrated oxidopolyborates [37][38][39]. The third step corresponds to the release of organic cations which ongoing over a wide temperature range.…”
Section: Thermal Analysissupporting
confidence: 86%
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“…The same behavior is entirely consistent with related hydrated oxidopolyborates [37][38][39]. The third step corresponds to the release of organic cations which ongoing over a wide temperature range.…”
Section: Thermal Analysissupporting
confidence: 86%
“…5 and 6. An intense bands are observed in the UV region of the spectra, at 235 and 311 nm, respectively for compound 1 and 2which can be referred to the π−π * and n−π * interactions [24,37].On the other hand, the characteristic bands of the octahedral coordination sphere of Co(II) metal ion appeared in the visible region at 510 nm and 660 nm for compound 1 and 512 and 661 nm for compound 2, well assigned to 4 T 1g (F)-> 4 T 1g (P) and 4 T 1g (F) -> 4 A 2g (F) transitions of Co(II) in octahedral coordination.…”
Section: Optical Propertiesmentioning
confidence: 99%
“…Details for individual compounds (2, 4-7) are given in the experimental section. This type of decomposition behaviour has been observed previously for other hydrated Ni (II) oxidoborates [33,[42][43][44][45][46][47][48] and more generally applies to the thermolysis of many hydrated transition-metal oxidopolyborates [30,33,35,37]. Powder XRD data were also obtained for this selection of Ni (II) oxidoborates (viz.…”
Section: Magnetic Spectroscopic Thermal and P-xrd Characterization Of Compounds 1-8supporting
confidence: 79%
“…The B-O bondlengths and OBO and BOB angles of the hexaborate(2-) ligand are in accord with previously reported data for this ligand including three very long B-O bondlengths (1.498( 6)-1.538( 6) o ; av. 1.517( 6) o ) to the three-coordinate O atom (O1) [28,29,48,51,52]. There is an intramolecular H-bond from an oxidoborate hydroxy group (containing O10) and the coordinated aqua ligand (containing O21), O10H10 … O21, with a O10 … O21 distance of 2.704(5) Å and a O10-H10-O21 angle of 144.9 o (Figure 3).…”
Section: Synthesis and General Discussionmentioning
confidence: 99%
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