Most supervised audio recognition systems developed to this point have used a testing set which includes the same categories as the training set database. Such systems are called closed-set recognition (CSR). However, audio recognition in real applications can be more complicated, where the datasets can be dynamic, and novel categories can ceaselessly be detected. Hence, in practice, the usual methods will assign to these novel classes labels which are often incorrect. This work aims to investigate audio open-set recognition (OSR) suitable for multi-classes classification recognition, with a rejection option for classes never seen by the system. A probabilistic calibration of a support vector machine classifier is utilized and formulated under the open-set scenario. For this, it is proposed to apply a threshold technique called peak side ratio (PSR) to the audio recognition task. A candidate label is first examined by a Platt-calibrated support vector machine (SVM) to produce posterior probabilities. The PSR is then used to characterize the distribution of posterior probabilities values. This process helps to determine a threshold in order to reject or accept a particular class. Our proposed method is evaluated on different variations of open sets, using wellknown metrics. Experimental results reveal that our proposed method outperforms previous OSR approaches over a wide range of openness values.