Spectral dispersion of light on a finite-size surface plasmon polaritonic (SPP) crystal has been studied. The angular wavelength separation of one or more orders of magnitude higher than in other state-of-theart wavelength-splitting devices available to date has been demonstrated. The two-stage process is responsible for the dispersion value, which involves conversion of the incident light into SPP Bloch modes of a nanostructure followed by the SPP Bloch waves refraction at the SPP crystal boundary. The high spectral dispersion achievable in plasmonic devices may be useful for integrated high-resolution spectroscopy in nanophotonic, optical communication and lab-on-a-chip applications. DOI: 10.1103/PhysRevLett.99.083901 PACS numbers: 42.79.Dj, 42.25.Fx, 78.67.ÿn, 78.68.+m Recent progress in photonics and integrated optics presents many challenges for development of micro-and nano-integrated components capable of routing and manipulating light waves in confined geometries. To this end, plasmonic devices offer a range of functionalities for guiding of light and its control with external signals, enhancing nonlinear interactions, and designing optical transmission and reflection properties, all with planar, subwavelength size components [1,2]. After development of many basic elements of two-dimensional (2D) surface plasmon polaritonic (SPP) optics [2], a search for additional functionalities in SPP-based devices continues to attract significant attention for applications in various areas of science and technology.One of the functionalities that has not yet been addressed with plasmonic waves is dispersion and spectral analysis. Since the first experiments by Newton on light dispersion in a glass prism, the spectral dispersion of light -that is, the dependence of generalized refractive index on frequency-is ubiquitous in applications ranging from spectroscopic devices to sensing and novel optical communication technologies. Very recently, new challenges have arisen for spectroscopic devices needed in optical switching and routing of information according to its frequency (color), to develop compact devices that can be integrated into photonic circuits of the future or into labon-a-chip applications for in situ spectral functionality. These cover high-resolution spectroscopy, wavelength demultiplexing of optical signals, ultrashort pulse analysis, and many others.Although free-space plane and concave gratings can achieve high values of spectral dispersion, their disadvantages are that they are bulky and require discrete optical components. The control of aberration is limited to a relatively narrow wavelength range, and additional components are also needed for coupling to optical fibers or waveguides [3,4]. Diffraction gratings based on planar waveguide technology are limited to a relatively small size because of the difficulty of controlling the substrate quality over a large area, and they suffer from strong scattering and require complex waveguide fabrication [4,5].Recently two-dimensional spectral dispersion...