The Organic Thermochemistry of Hydroxylamines, Oximes, Hydroxamic Acids and their Derivatives

Slayden, Suzanne W.; Liebman, Joel F.

doi:10.1002/9780470682531.pat0455

Cited by 9 publications

(13 citation statements)

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“…In addition, the effect of solvent on the proposed mechanism has also been investigated. Surprisingly little is known about the thermochemistry of O-substituted hydroxylamines, and for that matter about substituted hydroxylamines in general [63]. Can these catalyzed reactions provide such desired information?…”

Section: Issuementioning

confidence: 99%

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Interplay of thermochemistry and Structural Chemistry, the journal (volume 17, 2006) and the discipline

Ponikvar‐Svet

Liebman

2009

Struct Chem

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Section: Issuementioning

confidence: 99%

“…While isomerism was not observed for the first compound the presence of E and Z isomers was shown in the second and the third. It is to be acknowledged that the E-/Z-enthalpy difference is known for few oximes, much less oxime ethers such as the above compounds [63].…”

Section: Issuementioning

confidence: 99%

Interplay of thermochemistry and Structural Chemistry, the journal (volume 17, 2006) and the discipline

Ponikvar‐Svet

Liebman

2009

Struct Chem

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“…We are thwarted as the desired data are missing. Indeed, the enthalpy of formation of benzohydroxamic acid itself remains unknown as is the case for hydroxamic acids in general [221].…”

Section: Issuementioning

confidence: 99%

“…This is a novel species, perhaps in equilibrium with the isomeric benzisoxazole-N-oxide and/or benzo-1,2,3-dioxazine. In principle, its enthalpy of formation could be determined should the sublimation enthalpy of salicylaldehyde oxime be measured (and the enthalpy of formation of the solid remeasured, perchance [221] and requisite bond energies and acidities be determined using experiments related to the recent study of the enthalpy of formation of o-benzoquinone as derived from that of catechol [251].…”

Section: Issuementioning

confidence: 99%

Interplay of thermochemistry and Structural Chemistry, the journal (volume 19, 2008) and the discipline

et al. 2009

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“…Four stereoisomers of the ligand may be considered: (Z, Z), (Z, E), (E, Z), and (E, E). Their relative stability is unknown, and although this is not expected to be of much consequence to the analytical chemist [439], the organic chemist is not likely to have been of much help anyway even if it had been, given such problems as those with the energetics of the related, and more symmetric and hence simpler, a-diketone dioximes [440].…”

Section: Issuementioning

confidence: 99%

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

Ponikvar

Liebman

2008

Struct Chem

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In this study, we relate the contents of the journal Structural Chemistry for the calendar year 2007 and thermochemistry. The year's articles were briefly summarized and a thermochemical comment written to supplement them. Frequently questions were asked and future research was suggested.Keywords Structural Chemistry Á Thermochemistry Á Thermodynamics Á Enthalpy of formation Á Enthalpy of phase change Á Enthalpy of reaction As practiced disciplines, structural chemistry and thermochemistry are very often unrelated. In this study, these disciplines are linked as relations are explicitly made using the contents of the journal Structural Chemistry (Vol. 18) for the calendar year 2007 as a scaffold for our analysis, for our selected articles in the discipline of structural chemistry. These studies have been reviewed by us, where we give them a thermochemical flavor. While this commentary is most generally written in terms of brief summaries of literature papers involving enthalpies of formation and/or reaction, not uncommonly we raise questions and even suggest possible future research. We are not, however, going to give a thermochemical slant on book reviews, honorary dedications, and obituaries although these works will be cited in our text.As such, this article is a sequel to our earlier related reviews of Structural Chemistry for the calendar years 2000 through 2004 [1-5]. Reviews for 2005 and 2006 are currently being prepared. Issue 1In the first article in the first issue of Structural Chemistry for 2007, Hargittai [6] asserted that while research is currently usually carried out in big groups, the most important ideas, observations and discoveries still belong to individuals who have to bring down dogmas or open entirely new areas in science. This may bring solace to the thermochemical community in which research groups are generally small, and the number of new practitioners sadly few.In the past decade, the crystal engineering of multidimensional arrays and networks containing metal ions has achieved considerable progress because of the increased interest in the potential utility of these compounds as zeolite-like materials [7-11], catalysts [12], or magnetic materials [13][14][15]. The thermochemistry of these species is complicated by their inherent complexity: however, estimation approaches of their key thermochemical quantities are increasingly reliable [16]. In the second article of this issue, by Wang et al. [17], the versatility of malonate dianion as a ligand for the construction of extended networks with different topologies dependent on the coordination geometry of the metal ion was discussed. The synthesis and structure of a novel malonate-bridged copper(II) compound in which copper(II) ions have two different coordination environments in a novel three-dimensional (3D) network was described. Metal malonates have been studied from a

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The Organic Thermochemistry of Hydroxylamines, Oximes, Hydroxamic Acids and their Derivatives

Abstract: Introduction: Scope of the Chapter, Definitions of Key Terms and Sources of Data Hydroxylamines and N ‐Substituted Derivatives O ‐Substituted Hydroxylamine Derivatives (Alkoxylamines) Monooximes Glyoxime and Other Dio… Show more

Cited by 9 publications

References 72 publications

Interplay of thermochemistry and Structural Chemistry, the journal (volume 17, 2006) and the discipline

Interplay of thermochemistry and Structural Chemistry, the journal (volume 17, 2006) and the discipline

Interplay of thermochemistry and Structural Chemistry, the journal (volume 19, 2008) and the discipline

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

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