The orientation of free-radical addition to olefins

Abstract

S u m m a r y The rate and orientation of addition of hepta-olefins the substituent has virtually no effect on the rate of fluoropropyl radicals to a series of fluoro-olefins in the addition. Only with 1, l-difluoroethylene and 3,3,3-trigas phase has been determined by a competitive method. fluoropropene does there appear to be appreciable retarda-

Reactivities in Free-radical Polymerization

“…A more extended list (Table 8), taken from the work of Tedder and Walton and their colleagues, 36 illustrates this point more fully. A more extended list (Table 8), taken from the work of Tedder and Walton and their colleagues, 36 illustrates this point more fully.…”

Guest Encapsulation within Self‐Assembled Molecular Containers

“…The deepcavity host 2 with a hydrophobic rim takes up gaseous butane in aqueous solution to form a 2:2 complex (Figure 1 b). [8] In this case, capsule formation is templated by guest encapsulation. Without the guest, only monomeric 2 is present in solution, as could be shown with DOSY NMR spectroscopy.…”