THE OSMOTIC PRESSURE OF SUCROSE SOLUTIONS AT 30°.¹

Free-Solvent Model of Osmotic Pressure Revisited: Application to Concentrated IgG Solution under Physiological Conditions

“…As an example, Frazer and Myrick (in interaction parameters, n ij . We will investigate this model 1916) (32), in their work with aqueous sucrose solutions, with data obtained for high concentrated IgG in physiologic suggested that the free solvent in solution exhibits near ideal solution. The observed osmotic pressure data are also fitted behavior, provided that hydration and association are consid-to the virial expansion model based on mass concentration ered in determining the effective free-solvent concentration.…”

Understanding Nonidealities of the Osmotic Pressure of Concentrated Bovine Serum Albumin

“…As early as 1916, Frazer and Myrick (27) analyzed the non-idealities in aqueous sucrose solutions using a free-solvent model. More recently, other researchers, in a similar approach, based their models on the van't Hoff equation but only had limited success for protein solutions up to moderate concentrations (9, 28 -31).…”

Determining fouling‐independent component of critical flux in protein ultrafiltration using the free‐solvent‐based (FSB) model

“…As early as 1916, Frazer and Myrick 14 analyzed the nonidealities in aqueous sucrose solutions using a free-solvent model. More recently, other researchers, in a similar approach, based their models on the van't Hoff equation, but only had limited success for protein solutions up to moderate concentrations.…”