1983
DOI: 10.1016/0022-4596(83)90025-7
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The oxysulfide anion [NbS3O]3−: Synthesis and crystal structure of Ba6(NbS4)(NbS3O)3

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Cited by 6 publications
(3 citation statements)
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“…5a, 5b). While octahedral coordination of Nb is often observed in NbS 2 derivatives, tetrahedral coordination of Nb is exceptional and usually related to Nb 5+ (9). Such a high oxidation state is hard to be realized under the synthesis conditions used here.…”
Section: Resultsmentioning
confidence: 91%
“…5a, 5b). While octahedral coordination of Nb is often observed in NbS 2 derivatives, tetrahedral coordination of Nb is exceptional and usually related to Nb 5+ (9). Such a high oxidation state is hard to be realized under the synthesis conditions used here.…”
Section: Resultsmentioning
confidence: 91%
“…The very pronounced unsymmetrical ruffling of the porphyrinato core is probably related to these unsymmetrical orientations of the two handles relative to the normal of the 24-atom-core mean plane of the porphyrin. 21 Acknowledgment. We thank Dr. A.…”
mentioning
confidence: 99%
“…Ordering information is given on any current masthead page. (21) In [Zn(BH(Bipy)2P)], the two bipyridine handles present a quasi-planar trans conformation and lie almost parallel to the 24-atom-core mean plane of the porphyrin ring. The ruffling of the porphyrin is much less important than in the iron derivative.…”
mentioning
confidence: 99%