“…A large number of metastable metal alloys are known which can mainly be divided into groups such as supersaturated solid solutions, crystalline intermetallic compounds, quasicrystalline phases and metallic glasses. The main methods for the synthesis of metastable alloys are melt or solid quench (conventional casting, 1 rapid solidification, 2,3 laser pulse 4 ), condensation (vapor–gas, 5 sputtering, 6,7 electrodeposition, 8 chemical 9,10 ), irradiation (particle bombardment, 11,12 ion implantation, 13 ion beam mixing 14 ), mechanical cold working (ball milling, 15 cold rolling, 16 pressure 17 ) and solid-state reaction (multilayers, 18 single-source decomposition 19,20 ). Most of the works are devoted to the synthesis and study of metastable alloys in the form of thin films.…”